On the photochemical formation of CN,C2, and C3 radicals in cometary comae     

Tetsuo Yamamoto 《Earth, Moon, and Planets》1981,24(4):453-463

The formation of cometary CN, C₂ and C₃ radicals is investigated in a photochemical reaction scheme. From an analysis of the observed brightness profiles of these radicals, it is shown that CN is formed as a primary product in the photolysis of its parent molecules, whereas C₂ and C₃ are formed via two-step photodissociation of their parents. We suggest that major parent of C₂ is different species from those of CN and C₃ on the basis of the difference of the variation with heliocentric distance of the sublimation rate of the parents of these radicals. Parent molecules and reaction schemes for the formation of these radicals are discussed.  相似文献   

Molecular distribution in the comae of H2O-comets: An analytic model     

Tetsuo Yamamoto 《Earth, Moon, and Planets》1981,24(2):175-188

Density distribution in cometary comae resulting from photodissociation, ionization and ion-molecule reaction of H₂O is investigated in an analytic manner. It is assumed that particles expand isotropically around the nucleus, and that each species has its own constant radial velocity. Formulae for the density distribution of photochemical products are presented throught the coma, and approximate formulae are given for the distribution of ion-molecule reaction products in the inner coma. Characterictics of the density profile are discussed on the basis of these analytic formulae.  相似文献   

Chromium solubility in anhydrous Phase B     

Luca Bindi  Ekaterina A. Sirotkina  Andrey V. Bobrov  Fabrizio Nestola  Tetsuo Irifune 《Physics and Chemistry of Minerals》2016,43(2):103-110

The crystal structure and chemical composition of a crystal of (Mg_14?x Cr _x )(Si_5?x Cr _x )O₂₄ (x ≈ 0.30) anhydrous Phase B (Anh-B) synthesized in the model system MgCr₂O₄–Mg₂SiO₄ at 12 GPa and 1600 °C have been investigated. The compound was found to be orthorhombic, space group Pmcb, with lattice parameters a = 5.900(1), b = 14.218(2), c = 10.029(2) Å, V = 841.3(2) Å³ and Z = 2. The structure was refined to R ₁ = 0.065 using 1492 independent reflections. Chromium was found to substitute for both Mg at the M3 site (with a mean bond distance of 2.145 Å) and Si at the octahedral Si1 site (mean bond distance: 1.856 Å), according to the reaction Mg²⁺ + Si⁴⁺ = 2Cr³⁺. Such substitutions cause a reduction in the volume of the M3 site and an increase in the volume of the Si-dominant octahedron with respect to the values typically observed for pure Anh-B and Fe²⁺-bearing Anh-B. Taking into account that Cr³⁺ is not expected to be Jahn–Teller active, it appears that both the Cr³⁺–for–Mg and Cr³⁺–for–Si substitutions in the Anh-B structure decrease the distortion of the octahedra. Electron microprobe analysis gave the Mg_13.66(8)Si_4.70(6)Cr_0.62(4)O₂₄ stoichiometry for the studied phase. The successful synthesis of this phase provides new information for the possible mineral assemblages occurring in the Earth’s deep upper mantle and shed new light on the so-called X discontinuity that has been observed at 275–345 km depth in several subcontinental and subduction zone environments.  相似文献   

Stability and P–V–T equation of state of KAlSi3O8-hollandite determined by in situ X-ray observations and implications for dynamics of subducted continental crust material     

Norimasa Nishiyama  Robert Paul Rapp  Tetsuo Irifune  Takeshi Sanehira  Daisuke Yamazaki  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2005,32(8-9):627-637

In situ X-ray diffraction measurements of KAlSi₃O₈-hollandite (K-hollandite) were performed at pressures of 15–27 GPa and temperatures of 300–1,800 K using a Kawai-type apparatus. Unit-cell volumes obtained at various pressure and temperature conditions in a series of measurements were fitted to the high-temperature Birch-Murnaghan equation of state and a complete set of thermoelastic parameters was obtained with an assumed K′_300,0=4. The determined parameters are V _300,0=237.6(2) Å³, K _300,0=183(3) GPa, (?K _T,0/?T) _P =?0.033(2) GPa K^?1, a ₀=3.32(5)×10^?5 K^?1, and b ₀=1.09(1)×10^?8 K^?2, where a ₀ and b ₀ are coefficients describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. We observed broadening and splitting of diffraction peaks of K-hollandite at pressures of 20–23 GPa and temperatures of 300–1,000 K. We attribute this to the phase transitions from hollandite to hollandite II that is an unquenchable high-pressure phase recently found. We determined the phase boundary to be P (GPa)=16.6 + 0.007 T (K). Using the equation of state parameters of K-hollandite determined in the present study, we calculated a density profile of a hypothetical continental crust (HCC), which consists only of K-hollandite, majorite garnet, and stishovite with 1:1:1 ratio in volume. Density of HCC is higher than the surrounding mantle by about 0.2 g cm^?3 in the mantle transition zone while this relation is reversed below 660-km depth and HCC becomes less dense than the surrounding mantle by about 0.15 g cm^?3 in the uppermost lower mantle. Thus the 660-km seismic discontinuity can be a barrier to prevent the transportation of subducted continental crust materials to the lower mantle and the subducted continental crust may reside at the bottom of the mantle transition zone.  相似文献   

Aircraft Observations of the Development of Thermal Internal Boundary Layers and Scaling of the Convective Boundary Layer Over Non-Homogeneous Land Surfaces   总被引：1，自引：0，他引：1  

Michail A. Strunin  Tetsuya Hiyama  Jun Asanuma  Tetsuo Ohata 《Boundary-Layer Meteorology》2004,111(3):491-522

This study investigates the convective boundary layer (CBL) that develops over anon-homogeneous surface under different thermal and dynamic conditions. Analysesare based on data obtained from a Russian research aircraft equipped with turbulentsensors during the GAME-Siberia experiment over Yakutsk in Siberia, from April to June 2000.Mesoscale thermal internal boundary layers (MTIBLs) that radically modified CBLdevelopment were observed under unstable atmospheric conditions. It was found thatMTIBLs strongly influenced the vertical and horizontal structures of virtual potentialtemperature, specific humidity and, most notably, the vertical sensible and latent heatfluxes. MTIBLs in the vicinity of the Lena River lowlands were confirmed by clouddistributions in satellite pictures.MTIBLs spread through the entire CBL and radically modify its structure if the CBL isunstable, and strong thermal features on the underlying surface have horizontal scalesexceeding 10 km. MTIBL detection is facilitated through the use of special parameterslinking shear stress and convective motion.The turbulent structure of the CBL with and without MTIBLs was scaled usingthe mosaic or flux aggregate approach. A non-dimensional parameterL_Rau/L_hetero (where L_Rau is Raupach's length and L_hetero is the horizontal scale of the surface heterogeneity)estimates the application limit of similarity and local similarity scaling models forthe mosaic parts over the surface. Normalized vertical profiles of wind speed, airtemperature, turbulent sensible and latent heat fluxes for the mosaic parts withL_RauL_hetero < 1 could be estimated by typical scalingcurves for the homogeneous CBL. Traditional similarity scaling models for the CBLcould not be applied for the mosaic parts with L_Rau/L_hetero > 1.For some horizontally non-homogeneous CBLs, horizontal sensible heat fluxes werecomparable with the vertical fluxes. The largest horizontal sensible heat fluxes occurred at the top of the surface layer and below the top of the CBL.Formerly affiliated to the Frontier Observational Research System for Global ChangeFormerly affiliated to the Frontier Observational Research System for Global Change  相似文献   

Melting of enstatite from 13 to 18 GPa under hydrous conditions     

Akihiro Yamada  Tetsuo Irifune 《Physics of the Earth and Planetary Interiors》2004,147(1):45-56

Experiments on MgSiO₃ enstatite were conducted in the pressure range from 13 to 18 GPa under hydrous conditions in order to clarify the effect of water on the melting phase relations of enstatite at pressures corresponding to the Earth’s mantle transition zone. In some previous experiments [Geol. Soc. Am. Bull. 79 (1968) 1685; Phys. Earth Planet. Inter. 85 (1994) 237], incongruent melting behavior to form Mg₂SiO₄ forsterite and SiO₂ enriched liquid up to 5 GPa was observed, and congruent melting behavior at pressures up to 12 GPa was observed. Under hydrous conditions, we found that the melting reaction changes from congruent to incongruent at around 13.5 GPa. Liquid formed above 13.5 GPa is enriched in MgO component relative to MgSiO₃ because it coexists with stishovite (SiO₂). Moreover, the solidus temperature decreases drastically at around 13.5 GPa, in unison with the change in the melting reaction. The solidus temperature is about 1400 °C at 13 GPa, but approximately 900 °C at 15 GPa. Our results show that the liquidus phase changes from clinoenstatite to stishovite with increasing pressure and water content above 13.5 GPa. MgSiO₃ enstatite is one of the major constituent minerals in the Earth’s mantle, and it is expected that MgO-enriched liquid will be generated in the transition zone if water is present.  相似文献   

²³⁰Th/²³⁴U and ¹⁴C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan     

Keiichi  Sasaki  Akio  Omura  Tetsuo  Miwa  Yoshihiro  Tsuji  Hiroki  Matsuda  Toru  Nakamori  Yasufumi  Iryu  Tsutomu  Yamada  Yuri  Sato  Hiroshi  Nakagawa 《Island Arc》2006,15(4):455-467

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.  相似文献   

A Challenge of Water Purification in Dokai Bay, Japan     

Tetsuo Yanagi  Machiko Yamada  Manabu Suzuki 《Marine pollution bulletin》1999,38(12):10-1069

A history of water pollution and countermeasures for water purification in Dokai Bay, Japan are reviewed. Now, Dokai Bay suffers from the occurrences of red tides and oxygen-deficiency in summer. In order to prevent the occurrences of red tides and oxygen-deficiency, an ecological numerical model has been developed. The model experiments forecast that when the phosphorus or nitrogen load from land will be cut by 90% or 95%, respectively, red tides and oxygen-deficiency will not occur in Dokai Bay. If the industrial and sewage facilities are not sufficient to cut the nutrients load to the necessary degree, we have to consider other countermeasures such as cultivating bivalves and algae in order to decrease the nutrients concentration in the bay. International co-operation related to coastal zone management is also discussed.  相似文献   

Creep characteristics of frozen soils     

K. Takegawa  A. Nakazawa  K. Ryokai  S. Akagawa 《Engineering Geology》1979,13(1-4):197-205

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Phase transformations in the earth's mantle and subducting slabs: Implications for their compositions, seismic velocity and density structures and dynamics   总被引：3，自引：0，他引：3  

Tetsuo  Irifune 《Island Arc》1993,2(2):55-71

Abstract Phase transformations in model mantle compositions and those in subducting slabs have been reviewed to a depth of 800 km on the basis of recent high-pressure experimental data. Seismic velocity and density profiles in these compositions have also been calculated using these and other mineral physics data. The nature of the seismic velocity and density profiles calculated for a pyrolite composition was found to generally agree with those determined by seismic observations (e.g. PREM). The locations of the seismic discontinuities at 400 and 670 km correspond almost exactly to the depths where the transformations of the olivine component to denser phases take place. Moreover, the steep gradients in the seismic velocity/density profiles observed between these depths are qualitatively consistent with those expected from the successive transformations in the complementary pyroxene-garnet component in the pyrolite composition. Further, the calculated seismic velocity and density values agree well with those observed in the upper mantle and mantle transition region within the uncertainties attached to these calculations and observations. Pyrolite or peridotite compositions are thus most likely to represent the composition of the mantle above 670 km depth, although some degrees of chemical heterogeneity may exist in the transition region. The observed sharp discontinuous increases of seismic velocities and density at this depth may be attributed either to the phase transformation to a perovskite-bearing assemblage in pyrolite or to chemical composition changes. Density profiles in subducted slabs have been calculated along adequate geotherms assuming that the slabs are composed of the former oceanic crust underlain by a thicker harzburgitic layer. It is shown that the former oceanic crust is substantially less dense than the surrounding pyrolite mantle at depths below 670 km, while it is denser than pyrolite in the upper mantle and the transition region. The subducted former oceanic crust may be trapped in this region, forming a geochemically enriched layer at the upper mantle-lower mantle boundary. Thick and cool slabs may penetrate into the lower mantle, but the chemically derived buoyancy may result in strong deformation and formation of megalith structures around the 670 km seismic discontinuity. These structures are consistent with those detected by recent seismic tomography studies for subduction zones.  相似文献